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Preparation and characterization of nanocrystalline ZrO2-7%Y2O3 powders for thermal barrier coatings by high-energyball milling

Kirsten BOBZIN, Lidong ZHAO, Thomas SCHLAEFER, Thomas WARDA

《机械工程前沿（英文）》 2011年 第6卷 第2期   页码 176-181 doi: 10.1007/s11465-011-0220-4

摘要：

High-energy ball milling is an effective method to produce nanocrystalline oxides. In this study, a conventional ZrO2-7%Y2O3spray powder was ball-milled to produce nanocrystalline powders with high levels of crystalline disorders for deposition of thermal barrier coatings. The powder was milled both with 100Cr6 steel balls and with ZrO2-3%Y2O3 ceramic balls as grinding media. The milling time was varied in order to investigate the effect of the milling time on the crystallite size. The powders were investigated in terms of their crystallite sizes and morphologies by X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results show that under given milling conditions the powder was already nanostructured after 40 min milling. The crystallite size decreased significantly with increasing milling time within first 120 min. After that, a further increase of milling time did not lead to a significant reduction of the crystallite size. Ball-milling led to lattice microstrains. Milling with the steel balls resulted in finer nano-sized crystal grains, but caused the contamination of the powder. The nano-sized crystal grains coarsened during the heat-treatment at 1250°C.

关键词： nanostrucured powders     yttria stabilized zirconia (YSZ)     high-energy ball milling     thermal barrier coatings    

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Augmented hydrogen production by gasification of ball milled polyethylene with Ca(OH)

Giovanni Cagnetta, Kunlun Zhang, Qiwu Zhang, Jun Huang, Gang Yu

《环境科学与工程前沿（英文）》 2019年 第13卷 第1期 doi: 10.1007/s11783-019-1096-5

摘要：

PE ball milling pretreatment induces higher H2 production and purity by gasification.

Ca(OH)2 reacts at solid state with PE boosting H2 and capturing CO2.

Ca(OH)2 significantly reduces methanation side-reaction.

关键词： Hydrogen production     Gasification     Plastic waste     High energy ball milling    

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Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1416-4

摘要：

• Solvent-free chitosan oxidation is obtained by rapid mechanochemical reaction.

关键词： Chitosan     High energy ball milling     Mechanochemistry     Oxidation    

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Energy field-assisted high-speed dry milling green machining technology for difficult-to-machine metal

《机械工程前沿（英文）》 2023年 第18卷 第2期 doi: 10.1007/s11465-022-0744-9

摘要： Energy field-assisted machining technology has the potential to overcome the limitations of machining difficult-to-machine metal materials, such as poor machinability, low cutting efficiency, and high energy consumption. High-speed dry milling has emerged as a typical green processing technology due to its high processing efficiency and avoidance of cutting fluids. However, the lack of necessary cooling and lubrication in high-speed dry milling makes it difficult to meet the continuous milling requirements for difficult-to-machine metal materials. The introduction of advanced energy-field-assisted green processing technology can improve the machinability of such metallic materials and achieve efficient precision manufacturing, making it a focus of academic and industrial research. In this review, the characteristics and limitations of high-speed dry milling of difficult-to-machine metal materials, including titanium alloys, nickel-based alloys, and high-strength steel, are systematically explored. The laser energy field, ultrasonic energy field, and cryogenic minimum quantity lubrication energy fields are introduced. By analyzing the effects of changing the energy field and cutting parameters on tool wear, chip morphology, cutting force, temperature, and surface quality of the workpiece during milling, the superiority of energy-field-assisted milling of difficult-to-machine metal materials is demonstrated. Finally, the shortcomings and technical challenges of energy-field-assisted milling are summarized in detail, providing feasible ideas for realizing multi-energy field collaborative green machining of difficult-to-machine metal materials in the future.

关键词： difficult-to-machine metal material     green machining     high-speed dry milling     laser energy field-assisted milling     ultrasonic energy field-assisted milling     cryogenic minimum quantity lubrication energy field-assisted milling    

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Ball milling promoted direct liquefaction of lignocellulosic biomass in supercritical ethanol

Chunyan Yang, Xiaoliang Yuan, Xueting Wang, Kejing Wu, Yingying Liu, Changjun Liu, Houfang Lu, Bin Liang

《化学科学与工程前沿（英文）》 2020年 第14卷 第4期   页码 605-613 doi: 10.1007/s11705-019-1841-0

摘要： In the present work, ball milling was applied for the pretreatment of lignocellulose to obtain high conversion and bio-oil yield in supercritical ethanol. Ball milling substantially decreased the crystallinity and particle size of lignocellulose, thereby improving its accessibility in ethanol solvent. An increased bio-oil yield of 59.2% was obtained for the ball milled camphorwood sawdust at 300°C, compared with 39.6% for the original lignocellulose. Decreased crystallinity significantly benefited the conversion of the cellulose component from 60.8% to 91.7%, and decreased particle size was beneficial for the conversion of all components. The obtained bio-oil had a high phenolic content, as analyzed by gas chromatography-mass spectrometry. Methoxylation and retro-aldol condensation were observed during alcoholysis, and the reaction pathways of lignocellulose in supercritical ethanol were attributed to the action of free radicals.

关键词： ball milling     lignocellulose     supercritical ethanol     liquefaction     bio-oil    

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Erratum to: One-step ball milling-prepared nano Fe

Xingguo Guo, Qiuying Wang, Ting Xu, Kajia Wei, Mengxi Yin, Peng Liang, Xia Huang, Xiaoyuan Zhang

《环境科学与工程前沿（英文）》 2020年 第14卷 第4期 doi: 10.1007/s11783-020-1258-5

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One-step ball milling-prepared nano Fe

Xingguo Guo, Qiuying Wang, Ting Xu, Kajia Wei, Mengxi Yin, Peng Liang, Xia Huang, Xiaoyuan Zhang

《环境科学与工程前沿（英文）》 2020年 第14卷 第2期 doi: 10.1007/s11783-019-1209-1

摘要： • Nano Fe2O3 and N-doped graphene was prepared via a one-step ball milling method. • The maximum power density of Fe-N-G in MFC was 390% of that of pristine graphite. • Active sites like nano Fe2O3, pyridinic N and Fe-N groups were formed in Fe-N-G. • The improvement of Fe-N-G was due to full exposure of active sites on graphene. Developing high activity, low-cost and long durability catalysts for oxygen reduction reaction is of great significance for the practical application of microbial fuel cells. The full exposure of active sites in catalysts can enhance catalytic activity dramatically. Here, novel Fe-N-doped graphene is successfully synthesized via a one-step in situ ball milling method. Pristine graphite, ball milling graphene, N-doped graphene and Fe-N-doped graphene are applied in air cathodes, and enhanced performance is observed in microbial fuel cells with graphene-based catalysts. Particularly, Fe-N-doped graphene achieves the highest oxygen reduction reaction activity, with a maximum power density of 1380±20 mW/m2 in microbial fuel cells and a current density of 23.8 A/m2 at –0.16 V in electrochemical tests, which are comparable to commercial Pt and 390% and 640% of those of pristine graphite. An investigation of the material characteristics reveals that the superior performance of Fe-N-doped graphene results from the full exposure of Fe2O3 nanoparticles, pyrrolic N, pyridinic N and excellent Fe-N-G active sites on the graphene matrix. This work not only suggests the strategy of maximally exposing active sites to optimize the potential of catalysts but also provides promising catalysts for the use of microbial fuel cells in sustainable energy generation.

关键词： Microbial fuel cells     Air cathodes     Nano Fe2O3 and nitrogen-doped graphene     Oxygen reduction reaction    

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Precursor-driven structural tailoring of iron oxychloride for enhanced heterogeneous Fenton activity

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1533-1543 doi: 10.1007/s11705-023-2330-z

摘要： Iron oxychloride (FeOCl) is a unique layered material with tunable electronic properties. The conventional synthetic route of chemical vapor transition involves a thermodynamics-driven gas–solid interfacial reaction which often generates macroscopic crystals with stable facets. In this study, through analyzing the effects of the synthetic parameters on the FeOCl synthesis, we discovered the dominant contribution of the α-Fe2O3 precursors on the chemical property of the FeOCl product, and subsequently developed a highly-controllable synthetic route of tailoring the FeOCl structures into small sizes and exposed high-energy facets via a facile and scalable mechanical-chemical approach. The synthesized products could be systematically tuned by the ball-milling conditions of the α-Fe2O3 precursors. With increased milling time, the FeOCl crystallites demonstrated reduced sizes and more exposed (110) facets. Intriguingly, these small-sized FeOCl catalysts exhibited much faster Fenton-like kinetics than the pristine macroscopic FeOCl materials. Specifically, FeOCl catalysts with a 12-hour milling time showed nearly 39 times higher efficiency toward phenol degradation than the pristine FeOCl. The structure-reactivity relationship was further elucidated using the combinatory analysis via density functional theory calculation, electron paramagnetic resonance and radical quenching probe experiments. This work provides a rationale for tailoring the surface structures of FeOCl crystallites for potential applications in environmental catalysis.

关键词： FeOCl     mechanical activation     heterogeneous Fenton reaction     ball milling    

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Events and reaction mechanisms during the synthesis of an Al

M. ABDELLAHI, M. ZAKERI, H. BAHMANPOUR

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 123-129 doi: 10.1007/s11705-013-1325-6

摘要： An Al O -TiB nanocomposite was successfully synthesized by the high energy ball milling of Al, B O and TiO . The structures of the powdered particles formed at different milling times were evaluated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Thermodynamic calculations showed that the composite formed in two steps via highly exothermic mechanically induced self-sustaining reactions (MSRs). The composite started to form at milling times of 9–10 h but the reaction was not complete. The remaining starting materials were consumed by increasing the milling time to 15 h. The XRD patterns of the annealed powders showed that aluminum borate is one of the intermediate products and that it is consumed at higher temperatures. Heat treatment of the 6-h milled sample at 1100 C led to a complete formation of the composite. Increasing the milling time to 15 h led to a refining of the crystallite sizes. A nanocomposite powder with a mean crystallite size of 35–40 nm was obtained after milling for 15 h.

关键词： ball milling     nanocomposite     Al2O3     TiB2    

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Multi-objective optimization of cutting parameters in high-speed milling based on grey relational analysis

Tao FU, Jibin ZHAO, Weijun LIU

《机械工程前沿（英文）》 2012年 第7卷 第4期   页码 445-452 doi: 10.1007/s11465-012-0338-z

摘要：

This paper investigates optimization problem of the cutting parameters in high-speed milling on NAK80 mold steel. An experiment based on the technology of Taguchi is performed. The objective is to establish a correlation among spindle speed, feed per tooth and depth of cut to the three directions of cutting force in the milling process. In this study, the optimum cutting parameters are obtained by the grey relational analysis. Moreover, the principal component analysis is applied to evaluate the weights so that their relative significance can be described properly and objectively. The results of experiments show that grey relational analysis coupled with principal component analysis can effectively acquire the optimal combination of cutting parameters and the proposed approach can be a useful tool to reduce the cutting force.

关键词： high-speed milling     grey relational analysis     principal component analysis     parameters optimization    

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快速球磨法高效实现各向同性气雾化MnAl 粉的纳米化制备 Article

J. Rial, E.M. Palmero, A. Bollero

《工程（英文）》 2020年 第6卷 第2期   页码 172-176 doi: 10.1016/j.eng.2019.03.013

摘要：

为了提高永磁体性能尤其是矫顽力，对气雾化MnAl粉末首次进行了30 s短时间球磨。结果表明，如此短的处理时间加上随后的退火可以高效地得到纳米结构和可控的相变。球磨过程中产生的微应变引起的缺陷与退火过程中形成的β相共同起到钉扎中心的作用，从而提高了矫顽力。研究表明，为了在磁化强度和矫顽力之间达到折中，在铁磁性τ-MnAl相和β相的形成之间找到一个平衡是很重要的。球磨（30 s）和退火后获得的矫顽力高达4.2 kOe (1 Oe = 79.6 A·m–1)，与早期文献报道的球磨时间超过20 h时的矫顽力相当。球磨后粉末的退火温度降低了75 ℃，矫顽力提高了2.5倍，而退火后的气雾化材料的剩磁基本保持不变，为合成各向同性的MnAl基粉末开辟了一条新的途径。

关键词： 永磁体     纳米结构     相变     MnAl     气雾化     球磨法    

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Coupling evaluation for material removal and thermal control on precision milling machine tools

《机械工程前沿（英文）》 2022年 第17卷 第1期   页码 12-12 doi: 10.1007/s11465-021-0668-9

摘要： Machine tools are one of the most representative machining systems in manufacturing. The energy consumption of machine tools has been a research hotspot and frontier for green low-carbon manufacturing. However, previous research merely regarded the material removal (MR) energy as useful energy consumption and ignored the useful energy consumed by thermal control (TC) for maintaining internal thermal stability and machining accuracy. In pursuit of energy-efficient, high-precision machining, more attention should be paid to the energy consumption of TC and the coupling relationship between MR and TC. Hence, the cutting energy efficiency model considering the coupling relationship is established based on the law of conservation of energy. An index of energy consumption ratio of TC is proposed to characterize its effect on total energy usage. Furthermore, the heat characteristics are analyzed, which can be adopted to represent machining accuracy. Experimental study indicates that TC is the main energy-consuming process of the precision milling machine tool, which overwhelms the energy consumption of MR. The forced cooling mode of TC results in a 7% reduction in cutting energy efficiency. Regression analysis shows that heat dissipation positively contributes 54.1% to machining accuracy, whereas heat generation negatively contributes 45.9%. This paper reveals the coupling effect of MR and TC on energy efficiency and machining accuracy. It can provide a foundation for energy-efficient, high-precision machining of machine tools.

关键词： machine tools     cutting energy efficiency     thermal stability     machining accuracy     coupling evaluation    

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机械化学法辅助荧光体浸出——稀土回收绿色工程法 Article

Steff Van Loy, Koen Binnemans, Tom Van Gerven

《工程（英文）》 2018年 第4卷 第3期   页码 398-405 doi: 10.1016/j.eng.2018.05.015

摘要：

稀土元素（REE）是设计和开发可持续能源应用的重要金属。从富含稀土元素的废物流中回收这些元素对实现独立、可持续的未来能源供应至关重要。本研究比较了从绿灯荧光体LaPO4:Ce3+,Tb3+回收稀土元素的两种机制：在湿法冶金酸浸工艺前与溶剂冶金机械化学浸出工艺前的机械活化机制。稀土元素浸出率在机械活化后增加60%，完成机械化学浸出工艺后增加98%。高分辨率透射电子显微镜（HR-TEM）成像揭露了系统元素浸出率增加的原因：浸出与浸出模式的改善可归因于晶体形态从单晶体到多晶体的转变。多晶形材料的雏晶尺寸减小至纳米级，使化学单元出现不规则填充，导致晶体内缺陷颗粒边界的增加，从而增强浸出工艺。发明了一种溶剂冶金法将机械活化与浸出工艺结合成一个步骤，这有利于降低运营成本。其结果是简单、高效的工艺提供了更加绿色的荧光体废物回收替代途经。

关键词： 机械化学     稀土元素     荧光体废物     球磨研磨     溶剂冶金    

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Processing of high-precision ceramic balls with a spiral V-groove plate

Ming FENG,Yongbo WU,Julong YUAN,Zhao PING

《机械工程前沿（英文）》 2017年 第12卷 第1期   页码 132-142 doi: 10.1007/s11465-017-0436-z

摘要：

As the demand for high-performance bearings gradually increases, ceramic balls with excellent properties, such as high accuracy, high reliability, and high chemical durability used, are extensively used for high-performance bearings. In this study, a spiral V-groove plate method is employed in processing high-precision ceramic balls. After the kinematic analysis of the ball-spin angle and enveloped lapping trajectories, an experimental rig is constructed and experiments are conducted to confirm the feasibility of this method. Kinematic analysis results indicate that the method not only allows for the control of the ball-spin angle but also uniformly distributes the enveloped lapping trajectories over the entire ball surface. Experimental results demonstrate that the novel spiral V-groove plate method performs better than the conventional concentric V-groove plate method in terms of roundness, surface roughness, diameter difference, and diameter decrease rate. Ceramic balls with a G3-level accuracy are achieved, and their typical roundness, minimum surface roughness, and diameter difference are 0.05, 0.0045, and 0.105 mm, respectively. These findings confirm that the proposed method can be applied to high-accuracy and high-consistency ceramic ball processing.

关键词： bearing     ceramic ball     spiral V-groove     kinematic analysis     trajectory    

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Microwave-induced high-energy sites and targeted energy transition promising for efficient energy deployment

《能源前沿（英文）》 2022年 第16卷 第6期   页码 931-942 doi: 10.1007/s11708-021-0771-y

摘要： Diverse interactions between microwaves and irradiated media provide a solid foundation for identifying novel organization pathways for energy flow. In this study, a high-energy-site phenomenon and targeted-energy transition mechanism were identified in a particular microwave heating (MH) process. Intense discharges were observed when microwaves were imposed on irregularly sized SiC particles, producing tremendous heat that was 8-fold the amount generated in the discharge-free case. Energy efficiency was thereby greatly improved in the electricity-microwaves-effective heat transition. Meanwhile, the dispersed microwave field energy concentrated in small sites, where local temperatures could reach 2000°C– 4000°C, with the energy density reaching up to 4.0 × 105 W/kg. This can be called a high-energy site phenomenon which could induce further processes or reactions enhancement by coupling effects of heat, light, and plasma. The whole process, including microwave energy concentration and intense site-energy release, shapes a targeted-energy transition mechanism that can be optimized in a controlled manner through morphology design. In particular, the discharge intensity, frequency, and high-energy sites were strengthened through the fabrication of sharp nano/microstructures, conferring twice the energy efficiency of untreated metal wires. The microwave-induced high-energy sites and targeted energy transition provide an important pathway for high-efficiency energy deployment and may lead to promising applications.

关键词： microwave discharge     high-energy sites     targeted-energy transition     morphology design     energy efficiency    

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标题 作者 时间 类型 操作

Preparation and characterization of nanocrystalline ZrO2-7%Y2O3 powders for thermal barrier coatings by high-energyball milling

Kirsten BOBZIN, Lidong ZHAO, Thomas SCHLAEFER, Thomas WARDA

期刊论文

Augmented hydrogen production by gasification of ball milled polyethylene with Ca(OH)

Giovanni Cagnetta, Kunlun Zhang, Qiwu Zhang, Jun Huang, Gang Yu

期刊论文

Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

期刊论文

Energy field-assisted high-speed dry milling green machining technology for difficult-to-machine metal

期刊论文

Ball milling promoted direct liquefaction of lignocellulosic biomass in supercritical ethanol

Chunyan Yang, Xiaoliang Yuan, Xueting Wang, Kejing Wu, Yingying Liu, Changjun Liu, Houfang Lu, Bin Liang

期刊论文

Erratum to: One-step ball milling-prepared nano Fe

Xingguo Guo, Qiuying Wang, Ting Xu, Kajia Wei, Mengxi Yin, Peng Liang, Xia Huang, Xiaoyuan Zhang

期刊论文

One-step ball milling-prepared nano Fe

Xingguo Guo, Qiuying Wang, Ting Xu, Kajia Wei, Mengxi Yin, Peng Liang, Xia Huang, Xiaoyuan Zhang

期刊论文

Precursor-driven structural tailoring of iron oxychloride for enhanced heterogeneous Fenton activity

期刊论文

Events and reaction mechanisms during the synthesis of an Al

M. ABDELLAHI, M. ZAKERI, H. BAHMANPOUR

期刊论文

Multi-objective optimization of cutting parameters in high-speed milling based on grey relational analysis

Tao FU, Jibin ZHAO, Weijun LIU

期刊论文

快速球磨法高效实现各向同性气雾化MnAl 粉的纳米化制备

J. Rial, E.M. Palmero, A. Bollero

期刊论文

Coupling evaluation for material removal and thermal control on precision milling machine tools

期刊论文

机械化学法辅助荧光体浸出——稀土回收绿色工程法

Steff Van Loy, Koen Binnemans, Tom Van Gerven

期刊论文

Processing of high-precision ceramic balls with a spiral V-groove plate

Ming FENG,Yongbo WU,Julong YUAN,Zhao PING

期刊论文

Microwave-induced high-energy sites and targeted energy transition promising for efficient energy deployment

期刊论文